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Acidizing
Introduction
The Acid Consortium was established in 1992 and has 18 members. The group investigates carbonate and fracture acidizing in vertical and inclined wellbores, as well as sandstone matrix acidizing.

Previous work
In fracture acidizing a method has been developed to measure diffusivity of acids vs. lithology, acid strength and temperature. Mass transfer rates of carbonates and dolomites have been measured vs. flow rate, acid viscosity and cell size. This has been put into a series of correlations to predict mass transfer in carbonates with and without leakoff and conductivity have been evaluated in a 100 sq. in cell to show methods to develop conductive channels.

The effectiveness of carbonate matrix acidizing has been measured in linear and radial cells with and without drilling mud vs. acid strength, temperature and rate, with oil present and with biologically generated acids. Sandstone acidizing effectiveness has been measured in large radial cores vs. typical linear core flow tests to show the differences that can be expected.

The consortium has evaluated the effectiveness of various organic acids and HF strengths on problem cores submitted by members to arrive at acid type and strength recommendations vs. formation lithology. HF acid diversion has been investigated using particulates of various types and sizes in dual hollow cores of various permeabilities and in multiple linear and radial core flow systems using foam vs. core permeability, foam quality, slug size and surfactant concentration with and without oil present.

Recent Work
During the 99 Program, fracture acidizing studies are measuring leakoff using various alternating gel and acid systems vs. permeability gel type and acid strength in multiple long cores. Conductivity tests are underway in a specially designed biaxial rock mechanics system to look at conductivity vs. closure for various etched volume ratios vs. rock mechanical properties (soft chalk to hard dolomite).

The observed results are being programmed into a finite element simulator to predict conductivity downhole based on etched area volume and mechanical properties at downhole conditions. The results will be placed into a program called SLFracAcid to predict the resulting conductivity and well productivity.

Carbonate matrix acidizing studies are being extended to a specially designed large scale wellbore model. Work will look at acid wash treatments in horizontal wells to evaluate the effectiveness of various rates, acid concentrations, and viscosity with and without damage and with permeability variations.

Diversion studies are concentrating on the evaluation of diversion techniques in carbonates such as viscosified acids, foams, emulsions and combinations thereof in multiple linear and radial cores. Tests will evaluate each technique vs. permeability contrast, with and without damage present.

Evaluation techniques include pressure drop, CAT scan imaging of wormholes and SEM analysis of fines at the wormhole tip. Matrix sandstone acidizing studies are being conducted in a newly devised radial flow simulator that allows the determination of HFacidizing effectiveness at realistic velocities up to 2 ft from the wellbore. The acid is pumped into a series of cores and flowed back as in an actual treatment.

Elemental analysis of the flowback samples and permeability vs. depth are measured vs. lithology, acid strength, pumping schedule and shut-in time. The data from these tests will be compared to field flowback sample results provided by members and can be used to calibrate newly developed HF acidizing models.

Membership to the Acid Consortium
Stim-Lab encourages new members so that research continues adding value to participating company's lines of business. First year membership includes copies of past years research results. Membership grants access to the "members only" web site which contains research updates, reports for download, plus any programs or spreadsheets developed within the program. Contact Us  for membership information